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Home / Lubricant Additive Components / Friction Modifiers / Molybdenum Dialkyldithiophosphate (MoDTP)

Molybdenum Dialkyldithiophosphate (MoDTP)

Molybdenum dialkyldithiophosphate (MoDTP, MO10SP, CAS 72030-25-2) — the classic oil-soluble organomolybdenum friction modifier, Mo 9.9% / S 12.65% / P 3.75%, that generates low-friction MoS₂ at high temperature to reduce friction and wear in engine oils.

Density at 20 °C 1020 kg/m³
Viscosity at 100 °C 9.8 mm²/s
Flash Point 170 °C
Molybdenum 9.9 %

Technical Specifications

PropertyUnitTypical ValueTest Method
AppearanceBrownish red / green liquidVisual
Density at 20 °Ckg/m³1020ASTM D4052
Viscosity at 100 °Cmm²/s9.8ASTM D445
Flash Point°C170ASTM D93
Molybdenum%9.9ASTM D4951
Sulfur%12.65ASTM D4951
Phosphorus%3.75ASTM D4951

* Typical values from batch production. Batch-specific COA available on request.

Technical content reviewed by the CheMost additives team · Specifications last reviewed

Molecular Structure

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Representative 3D structure of the molybdenum dithiophosphate complex — the molybdenum centre coordinated by two O,O-dialkyl dithiophosphate ligands and two oxygens. Illustrative geometry of MoO₂[(RO)₂PS₂]₂. Rendered with 3Dmol.js.

Molecular structure · organomolybdenum (MoDTP)

Molybdenum di(2-ethylhexyl) phosphorodithioate, [Mo(dtp)₂] · CAS 72030-25-2

An oil-soluble molybdenum dithiophosphate carrying Mo, S and P; it generates low-friction molybdenum disulfide (MoS₂) at the contact at high temperature.

What Is Molybdenum Dialkyldithiophosphate (MoDTP)?

CheMost-MO10SP is a molybdenum dialkyldithiophosphate (MoDTP) — an oil-soluble organomolybdenum friction modifier that delivers molybdenum, sulfur and phosphorus in one liquid molecule (Mo 9.9%, S 12.65%, P 3.75%). It is the classic, most widely used organomolybdenum additive and a key component of fuel-economy engine oils.

At high temperature and under boundary friction the molecule decomposes at the rubbing contact to form molybdenum disulfide (MoS₂) — a low-shear lamellar solid that fills the uneven friction interface, lowers the friction coefficient and strengthens the oil film for added antiwear protection.

MoDTP differs from its sister chemistries by what it carries. Unlike the phosphorus-free MoDTC and the sulfur- and phosphorus-free complex, MoDTP contains both phosphorus and sulfur — so it brings extra antiwear from the phosphorus, at the cost of adding to the formulation’s phosphorus (SAPS) budget.

How MoDTP Works

MoS₂ at high temperature

Under load and heat the Mo-S-P molecule decomposes to molybdenum disulfide (MoS₂) at the contact — a lamellar solid lubricant that shears easily and cuts friction.

Combined Mo + P antiwear

The phosphorus contributes its own antiwear film alongside the molybdenum friction film, so MoDTP delivers friction reduction with reinforced wear protection.

Lower friction coefficient

The MoS₂ film lowers the boundary/mixed-regime friction coefficient — the friction losses that drive engine fuel consumption.

Works with the ZDDP system

As an organomolybdenum dithiophosphate it integrates with the ZDDP antiwear chemistry already present in engine oils, sharing the Mo/Zn dithiophosphate exchange chemistry.

Molybdenum Friction Modifiers Compared — Where MoDTP Fits

CheMost offers three organomolybdenum friction modifiers that differ by chemistry and S/P content. The table places MoDTP against the others so you can pick by phosphorus budget, molybdenum level and SAPS target. All figures are from each grade’s data sheet.

GradeTypeS / PMolybdenumBest for
MoDTP (this page)DithiophosphateS yes · P yes9.9%Classic general-purpose engine-oil FM
MoDTCDithiocarbamateS yes · P-free10.0%Premium fuel-economy FM, low-P
Organomolybdenum ComplexMo-amine complexS-free · P-free6.28%Low-SAPS, ash-sensitive engine oils

MoDTP is the classic, cost-effective choice where its phosphorus is acceptable and even welcome for antiwear. Where phosphorus must be kept low, use the P-free MoDTC; where the oil must be lowest-SAPS and sulfur-free as well, use the S/P-free complex.

Applications

CheMost-MO10SP is used as the organomolybdenum friction modifier in formulations targeting the duties below:

Fuel-economy engine oils

Passenger-car and heavy-duty engine oils where MoS₂-based friction reduction is needed for fuel economy, and the additional phosphorus antiwear is within the SAPS budget.

Greases

High-load greases where the in-situ MoS₂ film lowers friction and the phosphorus reinforces wear protection.

Industrial & gear oils

Industrial and gear lubricants benefiting from a molybdenum solid-lubricant film plus phosphorus antiwear under boundary conditions.

Finished-oil performance approvals (e.g. API, ACEA or ILSAC fuel-economy specifications) belong to the fully formulated oil, not to an individual friction-modifier component.

Treat Rate

The data sheet specifies the product but not a per-application dosage, so the figures below are indicative, derived from the chemistry and our formulating experience — confirm the final level.

First-order estimate. Organomolybdenum FMs are dosed to a molybdenum target, typically ~300–1000 ppm Mo. For MoDTP at 9.9% Mo that is roughly 0.3–1.0% product — far less than organic friction modifiers, which run ~0.25–1%. Note that at this level MoDTP also adds phosphorus (3.75% P in the product) to the oil, which counts against the low-SAPS phosphorus limit.

MoDTP is used within the engine-oil antiwear/friction system alongside ZDDP; where the phosphorus budget is tight, the P-free MoDTC may be preferred. The exact level depends on the molybdenum target, the phosphorus limit, the base oil and the rest of the package.

Treat rates are indicative, not fixed dosages. CheMost can provide formulation and treat-rate support on request.

Formulating With MoDTP — Complementary Additives

ZDDP

MoDTP and ZDDP share dithiophosphate chemistry and the molybdenum/zinc exchange equilibria; together they provide the friction and antiwear backbone of an engine oil.

MoDTC (P-free option)

Where the phosphorus budget is tight, MoDTC delivers similar MoS₂ friction reduction without adding phosphorus — the low-P alternative within the same moly family.

Antioxidants

A balanced antioxidant system protects the oil and keeps the molybdenum friction chemistry in its effective window over the drain interval.

Detergents & dispersants

In an engine-oil package MoDTP works within the detergent-inhibitor system; the detergent/dispersant balance must not interfere with the molybdenum film.

Documentation, Qualification & Regulatory Support

Standard documentation — Certificate of Analysis (COA, per shipment), Technical Data Sheet (TDS) and Safety Data Sheet (SDS, GHS/CLP) — is provided. The full TDS is available on request rather than as a public download. Additional support is available on request:

Regulatory documentation

REACH, TSCA and country-specific market-registration documentation support available on request.

Third-party inspection

SGS / Intertek / BV pre-shipment inspection can be arranged on request.

Custom grades & packaging

Custom packaging and grades on request.

Formulation support

Friction-modifier and treat-rate guidance from our technical team.

Packaging & Supply

CheMost-MO10SP is stocked and shipped worldwide, with a typical lead time of 1–15 days and a 36-month shelf life at ambient temperature. Samples and quotations are answered within 12 hours.

Packaging

200 kg metal drum · 1000 kg IBC tank.

Minimum order

1 drum / 1 IBC — contact us for your quantity.

Incoterms

FOB · CIF · EXW, to suit your freight arrangement.

Loading ports

All major Chinese ports.

Frequently Asked Questions

What is molybdenum dialkyldithiophosphate (MoDTP)?

It is the classic oil-soluble organomolybdenum friction modifier (Mo 9.9%, S 12.65%, P 3.75%) that generates low-friction molybdenum disulfide (MoS₂) at the rubbing contact at high temperature. It reduces friction for fuel economy and adds antiwear, mainly in engine oils and greases.

MoDTP or MoDTC — which should I use?

Both form MoS₂. MoDTP contains phosphorus (extra antiwear, but it adds to the SAPS phosphorus budget); MoDTC is phosphorus-free for low-P oils. For a sulfur- and phosphorus-free, lowest-ash option, use the organomolybdenum complex.

Does MoDTP contain phosphorus?

Yes — 3.75% phosphorus per the data sheet, in addition to 9.9% molybdenum and 12.65% sulfur. The phosphorus adds antiwear but counts against the low-SAPS phosphorus limit, so check your formulation’s P budget.

What treat rate should I use?

Dose to a molybdenum target — typically ~300–1000 ppm Mo, which for this 9.9%-Mo grade is roughly 0.3–1.0% product. Account for the phosphorus it contributes. The exact level depends on the base oil and the rest of the package; our technical team can assist.

How is it supplied, and how fast can I get a sample?

It is supplied as a brownish-red/green liquid in 200 kg metal drums and 1000 kg IBC tanks with a 36-month shelf life, and shipped worldwide. As a manufacturer and sourcing partner (Est. 2013), CheMost answers sample and quotation requests within 12 hours.

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