Lubricant Additives & Specialty Chemicals | Manufacturer & Sourcing Partner | Jinzhou, China — Est. 2013
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Home / Lubricant Additive Components / Corrosion Inhibitors & Metal Deactivators / Benzotriazole Derivative (Oil-Soluble Metal Deactivator)

Benzotriazole Derivative (Oil-Soluble Metal Deactivator)

Oil-soluble benzotriazole derivative metal deactivator (CCI51) — an ash-free, liquid copper corrosion inhibitor (an aminomethyl/Mannich tolyltriazole derivative) that passivates copper and yellow metals and is synergistic with phenolic antioxidants such as BHT; for many lubricant types. Avoid direct contact with ZDDP.

Flash Point 150 °C
Density at 20 °C 998 kg/m³
Viscosity at 50 °C 12 mm²/s
Total Base Number 215 mgKOH/g

Technical Specifications

PropertyUnitTypical ValueTest Method
AppearanceYellow transparent liquidVisual
Flash Point°C150ASTM D93
Density at 20 °Ckg/m³998ASTM D4052
Viscosity at 50 °Cmm²/s12ASTM D445
Total Base NumbermgKOH/g215ASTM D2896
Color1.5ASTM D1544
RPVOT (BVOT)min95ASTM D2272
Solubility (mineral Group I/II/III)%>10

* Typical values from batch production. Batch-specific COA available on request.

Technical content reviewed by the CheMost additives team · Specifications last reviewed

Molecular Structure

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Representative 3D structure of an oil-soluble benzotriazole aminomethyl (Mannich) derivative — a methylbenzotriazole ring carrying an aminomethyl group and a branched amine that give oil solubility and the high base number. Illustrative; the exact grade structure is proprietary. Rendered with 3Dmol.js.

Molecular structure · benzotriazole metal deactivator

Oil-soluble benzotriazole (tolyltriazole) aminomethyl derivative — benzotriazole ring + aminomethyl + branched amine (ash-free, no metal)

An oil-soluble, liquid benzotriazole derivative — the benzotriazole ring chemisorbs on copper; the aminomethyl/amine group makes it oil-soluble and basic.

What Is the Benzotriazole Derivative Metal Deactivator (CCI51)?

CheMost-CCI51 is an oil-soluble, oxidation-resistant metal deactivator and copper corrosion inhibitor — an aminomethyl (Mannich) derivative of benzotriazole (a methylbenzotriazole/tolyltriazole derivative). It effectively inhibits the corrosion of copper and other metals, and is supplied as an easy-to-add yellow liquid.

Benzotriazole is the classic copper-and-yellow-metal passivator: the triazole ring chemisorbs onto the metal to form a protective barrier film that both stops corrosion and removes copper’s catalytic effect on oil oxidation. Pure benzotriazole (BTA) is a solid, though; turning it into an aminomethyl derivative makes it oil-soluble and liquid for direct addition into finished oils, and gives it a high base number (TBN 215) from the amine group.

Two formulation points define how CCI51 is used, both noted on the data sheet: it is synergistic with phenolic antioxidants such as BHT, and — because of its basic amine structure — direct contact with ZDDP should be avoided. It is ash-free and suited to many lubricant types.

How CCI51 Works

Triazole chemisorbs on copper

The benzotriazole ring bonds to the copper surface to form a tightly-held barrier film, passivating copper and yellow metals against corrosion.

Oil-soluble, liquid form

The aminomethyl derivatisation makes the triazole oil-soluble and pourable, so it can be metered straight into finished oils — unlike solid benzotriazole, which must be dissolved.

Synergy with phenolic antioxidants

By removing copper’s oxidation catalysis, it works hand-in-hand with phenolic antioxidants; the data sheet notes synergy with BHT.

Keep separate from ZDDP

Because of its basic amine structure, direct contact with ZDDP should be avoided — add the two at different points in the blend rather than pre-mixing them.

Metal Deactivators Compared — Where CCI51 Fits

CheMost offers both classic copper-passivation routes plus the solid benzotriazole. The table places CCI51 against them so you can pick by heterocycle, form and the system you are protecting. All figures are from each grade’s data sheet.

GradeHeterocycleFormBest for
CCI51 (this page)Benzotriazole derivativeLiquid, oil-solubleGeneral copper passivation; synergy with phenolic antioxidants
CCI61Thiadiazole (DMTD), S 27.5%Liquid, oil-solubleCopper protection in high-sulfur / active-sulfur EP systems
Benzotriazole (BTA)BenzotriazoleSolid (granules)The pure, granular copper corrosion inhibitor / VCI

CCI51 is the liquid, oil-soluble way to get benzotriazole copper protection — choose it over solid BTA when pourable handling and direct addition matter; choose the thiadiazole when the system carries active sulfur.

Applications

CheMost-CCI51 is used as the copper corrosion inhibitor / metal deactivator in formulations targeting the duties below:

Industrial & turbine oils

Copper and yellow-metal passivation in industrial, turbine and circulating oils, where copper catalysis must be suppressed for long oil life.

Hydraulic oils

Protection of bronze and brass components in hydraulic systems, dosed as an easy-to-handle liquid.

Engine oils & greases

Copper/lead bearing protection and oxidation-catalysis control in engine oils and greases.

Metalworking fluids

Copper and yellow-metal corrosion control in metalworking oils and fluids.

Finished-oil performance approvals belong to the fully formulated oil, not to an individual additive component.

Treat Rate

The data sheet specifies the product but not a per-application dosage, so the figures below are indicative, derived from the chemistry and our formulating experience — confirm the final level.

First-order estimate. Triazole metal deactivators work at very low treat — roughly 0.02–0.5% (often below 0.1%), dosed to a copper-strip (ASTM D130) target. A small amount passivates the copper surface; over-treating gives little extra benefit.

Add CCI51 to work with the phenolic antioxidant system, and pre-blend it separately from ZDDP to avoid direct contact. The exact level depends on the copper content of the system and the rest of the package.

Treat rates are indicative, not fixed dosages. CheMost can provide formulation and treat-rate support on request.

Formulating With CCI51 — Complementary Additives

Phenolic antioxidant (BHT)

The data sheet notes CCI51 is synergistic with BHT: removing copper’s oxidation catalysis lets the phenolic antioxidant protect the oil more effectively.

Thiadiazole metal deactivator

For broad protection, the benzotriazole and thiadiazole routes can be combined — the thiadiazole adds reactive-sulfur protection in high-sulfur systems.

ZDDP (keep separate)

ZDDP is a normal co-additive, but because of CCI51’s basic structure, the two should not be in direct contact — add them at different stages of the blend.

Solid benzotriazole (BTA)

Where the solid granular form is preferred (or for vapour-phase corrosion inhibition), the pure benzotriazole is the alternative form of the same copper chemistry.

Documentation, Qualification & Regulatory Support

Standard documentation — Certificate of Analysis (COA, per shipment), Technical Data Sheet (TDS) and Safety Data Sheet (SDS, GHS/CLP) — is provided. The full TDS is available on request rather than as a public download. Additional support is available on request:

Regulatory documentation

REACH, TSCA and country-specific market-registration documentation support available on request.

Third-party inspection

SGS / Intertek / BV pre-shipment inspection can be arranged on request.

Custom grades & packaging

Custom packaging and grades on request.

Formulation support

Metal-deactivator and treat-rate guidance from our technical team.

Packaging & Supply

CheMost-CCI51 is stocked and shipped worldwide, with a typical lead time of 1–15 days and a 36-month shelf life at ambient temperature. Samples and quotations are answered within 12 hours.

Packaging

25 kg metal drum · 200 kg metal drum.

Minimum order

By drum — contact us for your quantity.

Incoterms

FOB · CIF · EXW, to suit your freight arrangement.

Loading ports

All major Chinese ports.

Frequently Asked Questions

What is a benzotriazole derivative metal deactivator?

It is an oil-soluble copper corrosion inhibitor made by converting benzotriazole into an aminomethyl (Mannich) derivative — a methylbenzotriazole/tolyltriazole derivative. The triazole ring passivates copper and yellow metals; the amine group makes it a pourable liquid with a high base number (TBN 215) for direct addition into finished oils.

How is it different from solid benzotriazole (BTA)?

Same copper-passivating chemistry, different form. Pure BTA is a solid that must be dissolved; CCI51 is the oil-soluble liquid derivative that meters straight into the oil. Choose CCI51 for pourable handling and direct addition; choose solid BTA where the granular form or vapour-phase inhibition is wanted.

Why should I avoid contact with ZDDP?

CCI51’s basic amine structure can interact directly with ZDDP, so the data sheet advises against direct contact. In practice, add the two at different points in the blend rather than pre-mixing them; both can still be in the finished oil.

What treat rate should I use?

Triazole metal deactivators work at very low levels — typically about 0.02–0.5% (often below 0.1%), dosed to a copper-strip (ASTM D130) target. The exact level depends on the copper content of the system and the rest of the package; our technical team can assist.

How is it supplied, and how fast can I get a sample?

It is supplied as a yellow liquid in 25 kg and 200 kg metal drums with a 36-month shelf life, and shipped worldwide. As a manufacturer and sourcing partner (Est. 2013), CheMost answers sample and quotation requests within 12 hours.

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